105380-30-1Relevant academic research and scientific papers
2-phenylthio-3,3,3-trifluoropropene, its sulfoxide and sulfone : Synthesis and reactivity in 1,3-dipolar cycloadditions
Plancquaert, Marie-Aimee,Redon, Martine,Janousek, Zdenek,Viehe, Heinz G.
, p. 4383 - 4396 (2007/10/03)
Derivatives of 3,3,3-trifluoropropene 1 : α-sulfide 2, sulfoxide 3, sulfone 4 and bromide 6 are useful trifluoromethylated synthons. On reaction with diazo compounds, these derivatives can afford trifluoromethyl substituted pyrazolines, pyrazoles, cyclopropanes or allylsulfones in fair to excellent yields. 1,3-Dipolar cycloaddition of trifluoropropene derivatives 2-4 with N-benzyl-azomethine ylide provides disubstituted 3-trifluoromethyl-pyrrolidines.
1-TRIFLUOROMETHYLVINYL ALKYL (ARYL) SULFONES
Fokin, A. V.,Kolomiets, A. F.,Shkurak, S. N.,Kondrashov, N. V.,Mukhametshin, F. N.
, p. 2135 - 2140 (2007/10/02)
In the reaction of 1-trifluoromethyl-2-chloroethanesulfenyl chloride with ethylene and cyclopentene (20 deg C) the corresponding sulfides were obtained.After treatment with triethylamine they were easily converted into 1-trifluoromethylvinyl 2-chloroethyl
