105417-33-2Relevant academic research and scientific papers
Asymmetric Oxidation of Alkyl Aryl Selenides under Sharpless Oxidation Conditions
Shimizu, Toshio,Kobayashi, Michio,Kamigata, Nobumasa
, p. 2099 - 2101 (1989)
Optically active alkyl aryl selenoxides were synthesized by the asymmetric oxidation of corresponding selenides under Sharpless oxidation conditions.The absolute configurations of the optically active alkyl aryl selenoxides prepared were estimated by comp
Synthesis of Selenoxides by Oxidation of Selenides with t-Butyl Hypochlorite, and Its Application for Synthesis of Optically Active Selenoxide
Kobayashi, Michio,Ohkubo, Hiromi,Shimizu, Toshio
, p. 503 - 506 (2007/10/02)
An effective synthesis of selenoxides by the oxidation of selenides with t-butyl hypochlorite in the presence of methanol and pyridine followed by hydrolysis is described.This oxidation method is particularly effective for the oxidation of selenides which possess electron-withdrawing groups.A synthesis of partially optically active selenoxide with bulky substituents can be achieved using a novel oxidation method.
FIRST SYNTHESIS OF SIMPLE OPTICALLY ACTIVE SELENOXIDES
Davis, Franklin A.,Billmers, Joanne M.,Stringer, Orum D.
, p. 3191 - 3194 (2007/10/02)
Simple optically active selenoxides (5-11 percente.e.) were prepared using a kinetic resolution procedure and were demonstrated to be configurationally unstable as a result of acid catalyzed achiral hydrate formation.
