105453-64-3Relevant academic research and scientific papers
Synthesis, absolute configuration, and bacterial mutagenicity of the 8 stereoisomeric vicinal diol epoxides at the terminal benzo ring of carcinogenic dibenz[ a,h ]anthracene
Frank, Heinz,Funk, Mario,Oesch, Franz,Platt, Karl L.
experimental part, p. 2258 - 2268 (2012/06/15)
The synthesis of the 8 possible stereoisomeric diol epoxides (DEs) at the terminal benzo ring of carcinogenic dibenz[a,h]anthracene (DBA) is reported. trans-3,4-Dihydroxy-3,4-dihydro-DBA (1) afforded the 4 bay region DEs: the enantiomeric pairs of the ant
Reduction of ortho-Quinones to Dihydrodiols
Kundu, Nitya G.
, p. 1920 - 1923 (2007/10/02)
1,2-Naphthaquinone, 5-bromo-1,2-naphthaquinone and dibenzanthracene-3,4-quinone in the form of dibromo-intermediates were reduced to a mixture of cis- and trans-diols by the action of sodium borohydride in ethanol.An alternative synthesis of trans-3,4-dihydroxy-3,4-dihydrodibenzanthracene is also reported.
