1054567-01-9

Basic information

• Product Name: 1-azido-2-((E)-4-methylstyryl)benzene
• Synonyms: 1-azido-2-((E)-4-methylstyryl)benzene
• CAS NO: 1054567-01-9
• Molecular Weight: 235.288
• Mol File: 1054567-01-9.mol

Chemical Properties

• CAS DataBase Reference: 1-azido-2-((E)-4-methylstyryl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-azido-2-((E)-4-methylstyryl)benzene(1054567-01-9)
• EPA Substance Registry System: 1-azido-2-((E)-4-methylstyryl)benzene(1054567-01-9)

Safety Data

• Hazardous Substances Data: 1054567-01-9(Hazardous Substances Data)

Upstream product

• 823809-34-3 N-(2-aminobenzylidene)-4-methylaniline 
• 622-97-9 1-ethenyl-4-methylbenzene 
• 615-43-0 2-iodophenylamine 

Downstream Products

• 55577-25-8 2-(4-methylphenyl)-1H-indole 

Relevant articles and documents

Synthesis of 2-Substituted Indoles through Visible Light-Induced Photocatalytic Cyclizations of Styryl Azides

A visible light-induced photocatalytic intramolecular cyclization of styryl azides has been developed in the presence of the ruthenium complex Ru(bpy)3Cl2 (0.5 mol%) as photocatalyst at room temperature. The present photocatalytic strategy features operational simplicity as well as high functional group tolerance, and provides a facile access to various 2-substituted N-free indoles in good to excellent yields. Importantly, the present process can employ sunlight as the light source to afford the corresponding products without loss of reaction efficiency.

Dirhodium(II)-catalyzed intramolecular C-H amination of aryl azides

(Chemical Equation Presented) Azides to indoles: Dirhodium(II)-catalyzed decomposition of aryl azides was developed as a mild, functional group tolerant method for the synthesis of indoles (see scheme).