105495-19-0Relevant academic research and scientific papers
Conversion of carbamates to amidosulfones and amides. Synthesis of the [14C]-labeled antiobesity agent Ro23-7637
White, James D.,Blakemore, Paul R.,Milicevic, Selena,Choudhry, Satish C.,Cupano, Joseph,Serico, Lucia
, p. 1803 - 1806 (2007/10/03)
Matrix presented Carbamates of primary and secondary amines react with the dianion of methyl phenyl sulfone to yield amidosulfones. Alylation of the amidosulfone followed by reductive removal of the sulfonyl residue gives an amide.
Further Reactions in the Tetrahydroazocin-2(1H)-one Series
Ridley, Damon D.,Simpson, Gregory W.
, p. 687 - 698 (2007/10/02)
5,6,7,8-Tetrahydroazocin-2(1H)-one and the 3-phenylthio- and 3-phenylthiosulfonyl-substituted derivatives have been converted into the corresponding 2-ethoxy-5,6,7,8-tetrahydroazocines with Meerwin's reagent.Upon irradiation under mercury lamp at longer w
