105499-60-3

Upstream product

• 100-53-8 phenylmethanethiol 
• 105448-90-6 (1S,2S,6R,7R,9R)-(-)-2-(Benzylthio)-3-oxabicyclo<4.3.0>nonan-7,9,-diyl-bis(4-methylbenzolsulfonat) 
• 105448-91-7 (1S,2S,6R,7R,9R)-(-)-2-(Benzylthio)-3-oxabicyclo<4.3.0>nonan-7,9,-diyl-bis(4-brombenzolsulfonat) 
• 85249-07-6 (1S,4aR,5R,7R,7aS)-1-Benzylsulfanyl-octahydro-cyclopenta[c]pyran-5,7-diol 
• 105499-63-6 (4aR,5S)-5-Hydroxy-4,4a,5,6-tetrahydro-3H-cyclopenta[c]pyran-7-one 
• 105499-64-7 (1S,2S,6R,7S)-(-)-2-(Benzylthio)-7-hydroxy-3-oxabicyclo<4.3.0>nonan-9-on 
• 74552-31-1 (6R,7R)-(-)-7-Hydroxy-3-oxabicyclo<4.3.0>non-1-en-9-on 
• 82207-78-1 (1S,6R,7R)-(-)-2-(Benzylthio)-7-hydroxy-3-oxabicyclo<4.3.0>nonan-9-on 

Downstream Products

• 82207-81-6 (5R,6R,8R,9S)-(-)-1-Benzylthio-6,8-bis(4-nitrobenzoyloxy)iridan 
• 82207-81-6 (5R,6R,8S,9S)-(-)-1-Benzylthio-6,8-bis(4-nitrobenzoyloxy)iridan 
• 82207-81-6 (1S,2S,6R,7S,9S)-(-)-2-(Benzylthio)-3-oxabicyclo<4.3.0>nonan-7,9-diyl-bis(4-nitrobenzoat) 
• 105499-67-0 (1S,2S,6R,7S,9S)-(-)-2-(Benzylthio)-3-oxabicyclo<4.3.0>nonan-7,9-diyl-bis(4-phenylbenzoat) 
• 82207-84-9 (1S,2S,7R,8R)-10-Phenyl-4,9,11-trioxa-10-bora-tricyclo[6.3.1.0^2,7]dodecan-3-one 
• 88365-28-0 (Z)-7-{(1R,2S,3R,5R)-3,5-Bis-benzyloxy-2-[(E)-(R)-3-(tetrahydro-pyran-2-yloxy)-oct-1-enyl]-cyclopentyl}-hept-5-enoic acid 
• 88365-27-9 (Z)-7-{(1R,2S,3R,5R)-3,5-Bis-benzyloxy-2-[(E)-(S)-3-(tetrahydro-pyran-2-yloxy)-oct-1-enyl]-cyclopentyl}-hept-5-enoic acid 
• 88365-22-4 9,11-Dibenzyl-2-decarboxy-15-dehydro-6-(p-phenylbenzoyloxy)-2,3,4,5-tetranor-PGF_1β 
• 88424-55-9 9,11-Dibenzyl-2-decarboxy-15-dehydro-6-(p-phenylbenzoyloxy)-2,3,4,5-tetranor-12-epi-PGF_1β 
• 88391-24-6 9,11-Dibenzyl-2-decarboxy-6-(p-phenylbenzoyloxy)-2,3,4,5-tetranor-PGF_1β 
• 88391-25-7 9,11-Dibenzyl-2-decarboxy-6-(p-phenylbenzoyloxy)-2,3,4,5-tetranor-PGF1β 
• 88365-23-5 9,11-Dibenzyl-2-decarboxy-6-(p-phenylbenzoyloxy)-2,3,4,5-tetranor-12-epi-PGF_1β 
• 88391-23-5 Biphenyl-4-carboxylic acid 2-[(1R,2S,3R,5R)-3,5-bis-benzyloxy-2-((E)-(R)-3-hydroxy-oct-1-enyl)-cyclopentyl]-ethyl ester 
• 90664-39-4 (15S)-2-Decarboxy-6-hydroxy-15-methyl-9,11-bis(p-phenylbenzoyl)-2,3,4,5-tetranor-12-epi-PGF_1β 

Relevant academic research and scientific papers

Chemistry and Stereochemistry of Iridoids, VII. - Enantiomerically Pure Intermediates for the Synthesis of Diastereomeric 12-epi-Prostaglandins

6,3'-epi-Catalpol (8a) is yielded from catalpol (7a) by a four component inversion reaction. 8a subsequently is converted into (1S,2S,6R,7S)-(-)-2-(benzylthio)-7-hydroxy-3-oxabicyclononan-9-on (4).LiAlH4 reduction of 4 affords the diastereomeric 2-

Chemistry and Stereochemistry of Iridoids, II. - About the Correlative Determination of the Configuration of Unedoside

Identical (5R,6R,8S,9S)-(-)-6,8-dihydroxy-1-oxoiridane (12) is prepared from both unedoside (4a) and catalpol (1) the absolute configuration of which is known.Thus, the absolute configuration of all centers of chirality of 4a is established except for C-1