105501-87-9Relevant academic research and scientific papers
Thiation reactions of some active carbonyl compounds with sulfur transfer reagents
Huang, Nai-Zhong,Lakshmikantham,Cava, Michael P.
, p. 169 - 172 (2007/10/02)
Anthrone reacts with the sulfur transfer reagents dithiobisphthalimide and dithiobissuccinimide in the presence of pyridine to provide a simple synthesis of monothioanthraquinone. Products of a different nature, derived from two molecules of ketone, were obtained from acenaphthenone and from a variety of β-diketones. A unified mechanism for the formation of all of the observed products, based upon the generation of transient thione intermediates, is proposed and supported by trapping experiments.
