1055029-67-8

Upstream product

• 187100-64-7 (4S)-2-Methylpentadec-6-yn-4-ol 
• 187100-70-5 tert-Butyl-((R)-1-isobutyl-dodec-11-ynyloxy)-dimethyl-silane 
• 1026391-00-3 (E)-(2S,3R,15R)-2-Amino-15-(tert-butyl-dimethyl-silanyloxy)-17-methyl-octadec-4-ene-1,3-diol 
• 1027378-72-8 (S)-4-[(1R,13R)-13-(tert-Butyl-dimethyl-silanyloxy)-1-hydroxy-15-methyl-hexadec-2-ynyl]-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester 
• 1026610-51-4 (E)-(1S,2R,14R)-2,14-Bis-(tert-butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-16-methyl-heptadec-3-enylamine 
• 187100-66-9 (12R)-14-Methylpentadec-1-yn-12-ol 
• 57566-83-3 (S)-2-isobutyloxirane 
• 764-93-2 1-decyne 

Downstream Products

• 1054653-84-7 Methanesulfonic acid (1R,12R)-1-[(1S,2S)-1,3-bis-(tert-butyl-dimethyl-silanyloxy)-2-(toluene-4-sulfonylamino)-propyl]-12-(tert-butyl-dimethyl-silanyloxy)-14-methyl-pentadecyl ester 

Relevant academic research and scientific papers

Synthesis of sphingosine relatives. Part 19. Synthesis of penaresidin A and B, azetidine alkaloids with actomyosin ATPase-activating properties

Three stereoisomers of penaresidin A 1 and two stereoisomers of penaresidin B 2' (Scheme 5), azetidine alkaloids isolated from the Okinawan marine sponge Penares sp., have been synthesized.In the course of our synthetic study, the correct structure of penarisidin B has been shown to be not 2 but 2'.Natural penaresidin A is either (2S,3R,4S,15S,16S)- or (2S,3R,4S,15R,16R)-1 and natural penaresidin B is either (2S,3R,4S,15S)- or (2S,3R,4S,15R)-2'.