105545-15-1

Upstream product

• 774-48-1 (diethoxymethyl)benzene 
• 15562-19-3 9S-Dihydroerythronolide A aglycon 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 105544-98-7 5,7,9-tri-O-benzyl-2,3,6,8-tetradeoxy-2,4,6,8-tetra-C-methyl-L-threo-L-ido-nonose ethylene acetal 
• 123219-54-5 (4S,5S,6R)-2,2,5-Trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxane-4-carbaldehyde 
• 114114-47-5 Acetic acid (4S,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-ylmethyl ester 
• 114114-32-8 Acetic acid (4S,5S,6S)-2,2,5-trimethyl-6-((R)-1-methyl-2-oxo-ethyl)-[1,3]dioxan-4-ylmethyl ester 
• 128879-55-0 (2R,4R,5S,6R)-4-[(S)-2-((R)-Benzenesulfinyl)-1-methyl-ethyl]-6-[(1S,2R)-1,2-bis-(tert-butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxane 
• 128879-55-0 (2R,4R,5S,6R)-4-[(S)-2-((S)-Benzenesulfinyl)-1-methyl-ethyl]-6-[(1S,2R)-1,2-bis-(tert-butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxane 
• 129245-15-4 (S)-3-[(2R,4R,5S,6R)-6-[(1S,2R)-1,2-Bis-(tert-butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-1,1,1-triphenyl-butan-2-one 
• 128855-99-2 (2R,3R)-2-[(2R,4R,5S,6R)-6-{(1S,2R,3S)-2-Benzenesulfinyl-3-hydroxy-1-methyl-3-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-butyl}-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-pentane-2,3-diol 
• 128856-00-8 (2R,3R)-2-[(2R,4R,5S,6R)-6-{(1S,2R,3S)-3-Hydroxy-1-methyl-2-phenylsulfanyl-3-[(4R,5S,6R)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxan-4-yl]-butyl}-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-pentane-2,3-diol 
• 128879-57-2 (R)-2-((4S,5S,6R)-6-{(1R,3R)-3-[(2R,4S,5S,6R)-6-((1R,2R)-1,2-Dihydroxy-1-methyl-butyl)-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-1-hydroxy-1-methyl-butyl}-2,2,5-trimethyl-[1,3]dioxan-4-yl)-propionic acid 
• 129245-17-6 (2R,4R,5S,6R)-4-[(1S,2R)-1,2-Bis-(tert-butyl-dimethyl-silanyloxy)-1-methyl-butyl]-2-(4-methoxy-phenyl)-5-methyl-6-((S)-1-methyl-2-phenylsulfanyl-ethyl)-[1,3]dioxane 

Downstream Products

• 105545-16-2 (1S,2R,5R,6S,7R,8R,10R,12R,13R,17S)-5-Ethyl-6,7,12-trihydroxy-2,6,8,10,12,17-hexamethyl-15-phenyl-4,14,16-trioxa-bicyclo[11.3.1]heptadecane-3,9-dione 
• 26754-37-0 erythronolide A 

Relevant academic research and scientific papers

STEREO-CONTROLLED SYNTHESIS OF ERYTHRONOLIDES A AND B FROM 1,6-ANHYDRO-β-D-GLUCOPYRANOSE (LEVOGLUCOSAN). SKELETON ASSEMBLY IN (C9 - C13) + (C7 - C8) + (C1 - C6) SEQUENCE

Stereospecific syntheses of erythronolides A and B have been accomplished starting from 1,6-anhydro-β-D-glucopyranose (levoglucosan) in a uniform synthetic sequence.