10555-36-9Relevant academic research and scientific papers
THE SYNTHESIS AND BASE INDUCED HOMOKETONIZATION OF 5-SUBSTITUTED HOMOCUNEYL 4-ACETATES
Arts, N. B. M.,Weenen, H.,Klunder, A. J. H.,Zwanenburg, B.
, p. 2825 - 2830 (2007/10/02)
The synthesis of two 5-substituted homocuneyl 4-acetates viz 4-acetoxy-5-carbomethoxypentacyclo2.4.03.8.05.7>nonane (8) and 4-acetoxy-5-benzoylpentacyclo2.4.03.8.05.7>nonane (9) is described starting from dicarboxylic acid (10).The base induced cage opening of these acetates has been studied.It was found for 9 that the regiochemistry of this process is not affected by the carbonyl containing functionality at C5.Exclusive opening of the cyclopropanol ring is observed.
