1055905-29-7Relevant articles and documents
Dichloroenol ethers x-ray analysis in the mechanistic elucidation of ynol ethers formation
Darses, Benjamin,Philouze, Christian,Greene, Andrew E.,Poisson, Jean-Francois
, p. 1053 - 1059 (2012/01/05)
X-ray crystallographic data are provided for dichloroenol ethers (S,E)-2-(1-(1,2-dichlorovinyloxy)ethyl)-1,3,5-triisopropylbenzene (2) and (S,E)-2-(1-(1,2-dichloroprop-1-enyloxy)ethyl)-1,3,5-triisopropylbenzene (3). The former forms colorless crystals (or
Ynol ethers from dichloroenol ethers: Mechanistic elucidation through 35Cl labeling
Darses, Benjamin,Milet, Anne,Philouze, Christian,Greene, Andrew E.,Poisson, Jean-Francois
supporting information; experimental part, p. 4445 - 4447 (2009/05/07)
(Chemical Equation Presented) The mechanism of ynol ether formation from dichloroenol ethers, a decades-old transformation, has been studied by experimental and theoretical techniques to determine the relative importance of the Fritsch-Buttenberg-Wichell rearrangement (α-elimination) and β-elimination in the evolution of the intermediate carbenoid.