1055987-65-9

Usage

Structure

Brominated aromatic compound with a benzene ring substituted at the 1 and 2 positions with a bromine atom and a phenoxy group, respectively. The phenoxy group is further substituted with a methyl group at the 4 position.

Usage

Organic synthesis, building block for the preparation of various organic compounds, pharmaceutical and agrochemical industries, production of specialty chemicals and materials.

Hazard

Potentially hazardous chemical, proper safety precautions should be taken when handling and using it.

Upstream product

• 1072-85-1 o-fluorobromobenzene 
• 106-44-5 p-cresol 

Downstream Products

• 1412761-94-4 (2-(p-tolyloxy)phenyl)boronic acid 
• 1412761-21-7 trimethyl(2-(p-tolyloxy)phenyl)silane 
• 7320-51-6 2-methyldibenzofuran 

Relevant academic research and scientific papers

Quinoline Ligands Improve the Classic Direct C?H Functionalisation/Intramolecular Cyclisation of Diaryl Ethers to Dibenzofurans

The C?H functionalisation approach to the synthesis of dibenzofurans is hampered by a number of problems. Herein we describe the evolution of a cheap, bench stable quinoline ligand, which obviates most of the current limitations and allows for a high yielding synthesis of a range of valuable dibenzofurans. Dibenzofurans are important motifs in natural products and compounds with wide biological activity.

1,5-Migration of rhodium via C-H bond activation in catalytic decyanative silylation of nitriles

Unprecedented aryl-to-aryl 1,5-rhodium migration is involved in decyanative silylation of aryl cyanides bearing a tethered arene. The 1,5-migration proceeds through remote C-H bond activation. 1,5-Migration also occurs in other rhodium-catalyzed reactions, including borylation and oxidative Mizoroki-Heck reactions.