105601-72-7Relevant academic research and scientific papers
Stereospecific Cyclization of Vinyl Ether Alcohols. Facile Synthesis of (-)-Lardolure
Kaino, Makoto,Naruse, Yuji,Ishihara, Kazuaki,Yamamoto, Hisashi
, p. 5814 - 5815 (2007/10/02)
An efficient and stereospecific ring formation from unsaturated alcohols, which in turn are prepared by regio- and stereospecific ring opening of acetals, is described.
ASYMMETRIZATION OF MESO-CYCLIC KETONES USING HOMOCHIRAL ACETAL TEMPLATES
Naruse, Yuji,Yamamoto, Hisashi
, p. 6021 - 6030 (2007/10/02)
Employing the homochiral acetal template, asymmetrization of meso-substituted cyclohexanones is explored.By the use of optically-active 2,4-pentanediol as a chiral protecting group, highly diastereoselective acetal cleavage is achieved when treated with organoaluminum reagent.Dialkylaluminum amides are also effective reagents for this reaction.
ORGANOALUMINUM REAGENT AS A CHEMICAL TOOL FOR ASYMMETRIZATION
Naruse, Yuji,Yamamoto, Hisashi
, p. 1363 - 1366 (2007/10/02)
A new process is described for the asymmetrization of meso ketones using organoaluminum reagent.
