10561-27-0Relevant academic research and scientific papers
Ga(OTf)3-catalyzed direct substitution of alcohols with sulfur nucleophiles
Han, Xinping,Wu, Jimmy
supporting information; experimental part, p. 5780 - 5782 (2011/03/18)
It is reported that Ga(OTf)3 catalyzes the direct displacement of alcohols with sulfur nucleophiles. The products are versatile intermediates that can be utilized in carbon - carbon, carbon - sulfur bond formation or used in modified Julia olef
A facile and efficient microwave-mediated S-alkylation of thiophosphates
Pandey, Lokesh Kumar,Mazumder, Avik,Pathak, Uma
experimental part, p. 602 - 605 (2010/01/06)
A convenient, highly efficient, safe microwave-mediated S- alkylation of O,O'-dialkyl thiophosphate has been reported. Clean and rapid S-alkylation of thiophosphates can be achieved by irradiating a mixture of dialkylthiophosphate salt and alky! halide under microwave for a brief period. Alkylation occurs exclusively at sulfur to provide S-alkylated products. Through a simple workup, pure compounds have been obtained easily in good yields.
