105619-89-4Relevant academic research and scientific papers
Synthetic Studies on the ophiobolane Sesterterpenes: Construction of an Optically Pure, Advanced Tricyclic Intermediate for the Synthesis of Ceroplasteric Acid
Rigby, James H.,McGuire, Timothy,Senanayake, Chrisantha,Khemani, Kishan
, p. 3449 - 3458 (2007/10/02)
Tropone has been transformed into an optically pure tricyclic system that could serve as an advanced intermediate in the synthesis of ceroplastic acid.The sequence features a stereoselective Ireland ester enolate Claisen rearrangement followed by an intra
A General Approach to the Synthesis of C8-Oxygenated Guaianolides
Rigby, James H.,Wilson, Jo Ann Zbur
, p. 34 - 44 (2007/10/02)
Preparation of an advanced intermediate for the synthesis of several highly oxygenated members of the guaianolide family of sesquiterpene lactones is described.The key hydroxy lactone species is constructed from the readily available hydroazulene 3 via th
