1056249-68-3Relevant academic research and scientific papers
Synthesis of chiral porphyrins through Pd-catalyzed [3+2] annulation and heterochiral self-assembly
Mizumura, Masatoshi,Shinokubo, Hiroshi,Osuka, Atsuhiro
, p. 5378 - 5381 (2008)
Positive discrimination: Palladium-catalyzed [3+2] annulation of meso-bromoporphyrin with norbornene derivatives efficiently provides novel chiral meso, b-fused porphyrins with a rigid structure (as shown). A chiral benzoazanorbornene-fused zinc porphyrin assembles selectively to form the slipped cofacial dimer in a heterochiral association, which allows construction of a heterodimer from two porphyrin components through chiral discrimination. (Chemical Equation Presented)
