105633-70-3Relevant academic research and scientific papers
Solid-state structure of 1,2-dimethoxybenzene (veratrole) and related methoxybenzenes. X-Ray crystallography and 13C nuclear magnetic resonance tensor analysis
Gerzain, Marielle,Buchanan, Gerald W.,Driega, Alex B.,Facey, Glenn A.,Enright, Gary,Kirby, Robert A.
, p. 2687 - 2693 (1996)
We present here the single crystal X-ray structure of 1,2-dimethoxybenzene which reveals the methoxy groups to be trans and twisted out of the plane by -5.0 and 8.6°. Using variable spinning rate 13C CP MAS NMR spectroscopy, the principal shiel
Ortho-metallation of anthracene derivative: Problem and solution
Matsumoto, Takashi,Kakigi, Hirotoshi,Suzuki, Keisuke
, p. 4337 - 4340 (2007/10/02)
Ortho-metallation of anthracene derivative with alkyllithium is hampered by the preferential attack of the anion to the C(9) and/or C(10) positions. Use of n-BuLi-t-BuOK effected a clean and regioselective metallation at C(2) and subsequent reaction with
