105676-45-7

Upstream product

• 5418-86-0 tris(methylthio)methane 
• 99315-76-1 (5S)-5-(tert-butyldiphenylsiloxymethyl)-2(5H)-furanone 
• 39090-54-5 tris(methylthio)methyl lithium 
• 21461-84-7 (2S)-tetrahydro-5-oxofuran-2-carboxylic acid 
• 56-86-0 L-glutamic acid 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 5336-08-3 D-Ribono-1,4-lactone 
• 99315-75-0 (-)-5-O-(diphenyl-t-butylsilyl)-2,3-O-(thiocarbonyl)-D-ribono-1,4-lactone 
• 92512-33-9 (3R,4S,5R)-5-((tert-butyldiphenylsilyloxy)methyl)-3,4-dihydroxydihydrofuran-2(3H)-one 
• 106731-86-6 (S)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-3-phenylselanyl-dihydro-furan-2-one 
• 32780-06-6 (5S)-5-(hydroxymethyl)-2-oxo-tetrahydrofuran 
• 106820-44-4 (4S,5S)-5-{[(tert-butyldiphenylsilyl)oxy]methyl}-4-[tri(methylthio)methyl]tetrahydrofuran-2-one 

Downstream Products

• 105676-50-4 (R)-5-[(R)-1-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-ethyl]-3-phenylsulfanyl-dihydro-furan-2-one 
• 105676-34-4 (3R,4S,5R,7S)-1,4,9-trihydroxy-3,5,7-trimethyl-9-O-tert-butyldiphenylsilyl-nonane 
• 115495-41-5 1-O-tert-butyldiphenylsilyl-3-deoxy-4,5-O-isopropylidene-3-C-methyl-D-arabinitol 
• 105676-32-2 (S)-5-[(1R,3S)-5-(tert-Butyl-diphenyl-silanyloxy)-1,3-dimethyl-pentyl]-5H-furan-2-one 
• 105676-56-0 3,4,5,6-tetradeoxy-1,2-O-isopropylidene-3,5-di-C-methyl-7-O-tert-butyldiphenylsilyl-D-arabino-heptitol 
• 105676-33-3 (4R,5S)-5-[(1R,3S)-5-(tert-Butyl-diphenyl-silanyloxy)-1,3-dimethyl-pentyl]-4-methyl-dihydro-furan-2-one 
• 105676-54-8 3,5,6-dideoxy-1,2-O-isopropylidene-3,5-di-C-methyl-7-O-tert-butyldiphenylsilyl-D-altro-heptitol 
• 115495-42-6 3-deoxy-3-C-methyl-1-O-(2,4,6-triisopropyl)benzenesulfonyl-D-arabinitol 
• 105676-55-9 Methanesulfonic acid (1R,2R)-4-(tert-butyl-diphenyl-silanyloxy)-1-[(S)-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-2-methyl-butyl ester 
• 105676-37-7 (3R,5S,7S)-1,9-dihydroxy-3,5,7-trimethyl-9-O-tert-butyldiphenylsilyl-1-O-triphenylmethyl-nonane 
• 105676-35-5 (3R,4S,5R,7S)-9-(tert-Butyl-diphenyl-silanyloxy)-3,5,7-trimethyl-1-trityloxy-nonan-4-ol 
• 115708-95-7 2,4,6-Triisopropyl-benzenesulfonic acid (2S,3R,5S)-7-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-3,5-dimethyl-heptyl ester 
• 115479-71-5 (4R,5R,7S)-9-(tert-Butyl-diphenyl-silanyloxy)-4-hydroxy-5,7-dimethyl-2-phenylselanyl-nonanoic acid 
• 115479-72-6 (R)-5-[(1R,3S)-5-(tert-Butyl-diphenyl-silanyloxy)-1,3-dimethyl-pentyl]-3-phenylselanyl-dihydro-furan-2-one 

Relevant academic research and scientific papers

STEREOCHEMICAL CONTROL OF NATURE'S BIOSYNTHETIC PATHWAYS: A GENERAL STRATEGY FOR THE SYNTHESIS OF POLYPROPIONATE-DERIVED STRUCTURAL UNITS FROM A SINGLE CHIRAL PROGENITOR

A general strategy that permits the stereocontrolled construction of acyclic chains containing vicinal and/or alternating alkyl and hydroxy substituents is presented.Structural subunits of ionomycin were synthesized from a common chiral intermediate.

A Versatile Protocol for the Stereocontrolled Elaboration of Vicinal Secondary and Tertiary Centers of Relevance to Natural Product Synthesis

Chiral butenolides derived from L-glutamic acid, D-ribonolactone, or D-mannitol are versatile templates from the stereocontrolled introduction of functional groups.Vicinal and/or alternating patterns of secondary and tertiary substitution can be attained