105679-15-0

Basic information

• Product Name: 1-Cyclopentene-1-carboxaldehyde, 2-[(2-oxo-2-phenylethyl)amino]-
• CAS NO: 105679-15-0
• Molecular Formula: C14H15NO2
• Molecular Weight: 229.279
• Mol File: 105679-15-0.mol

Chemical Properties

• CAS DataBase Reference: 1-Cyclopentene-1-carboxaldehyde, 2-[(2-oxo-2-phenylethyl)amino]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Cyclopentene-1-carboxaldehyde, 2-[(2-oxo-2-phenylethyl)amino]-(105679-15-0)
• EPA Substance Registry System: 1-Cyclopentene-1-carboxaldehyde, 2-[(2-oxo-2-phenylethyl)amino]-(105679-15-0)

Safety Data

• Hazardous Substances Data: 105679-15-0(Hazardous Substances Data)

Upstream product

• 7568-93-6 2-Amino-1-phenylethanol 
• 10472-24-9 methyl 2-oxocyclopentane-1-carboxylate 
• 611-10-9 2-ethoxycarbonyl-1-cyclopentanone 
• 127441-73-0 β-hydroxyphenethylamino-2 cyclopentene-1 carboxylate d'ethyle 
• 105679-13-8 2-(2-Hydroxy-2-phenyl-ethylamino)-cyclopent-1-enecarboxylic acid methyl ester 

Relevant articles and documents

Synthese de derives indoliques, d'oxazoles et de quinolones par thermolyse d'enaminoesters cycliques a cinq et six chainons

Flow pyrolysis of cyclic enaminoesters 1-9 provides various heterocyclic compounds resulting from intramolecular thermal rearrangement of intermediate iminoketenes generated in the first reaction step.The thermal behaviour of these cyclic enaminoesters is

THERMOLYSE COMPAREE D'ENAMINOESTERS CYCLIQUES A CINQ ET SIX CHAINONS : SYNTHESE DE TETRAHYDROINDOLES ET D'OXAZOLES

The thermal behaviour of cyclic enaminoesters 1a-d shows a divergence of chemioselectivity as a function of ring size : six and five ring derivatives lead respectively to tetrahydroindoles (3a,b and 4a,b) and oxazole (5c,d).These results may be rationalized by geometrical constraints during the electrocyclisation of intermediate azomethine ylides 5.