105688-43-5

Basic information

• Product Name: O-(4-phenylbut-3-yn-1-yl) Se-phenyl selenocarbonate
• Synonyms: O-(4-phenylbut-3-yn-1-yl) Se-phenyl selenocarbonate
• CAS NO: 105688-43-5
• Molecular Weight: 329.257
• Mol File: 105688-43-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: O-(4-phenylbut-3-yn-1-yl) Se-phenyl selenocarbonate(CAS DataBase Reference)
• NIST Chemistry Reference: O-(4-phenylbut-3-yn-1-yl) Se-phenyl selenocarbonate(105688-43-5)
• EPA Substance Registry System: O-(4-phenylbut-3-yn-1-yl) Se-phenyl selenocarbonate(105688-43-5)

Safety Data

• Hazardous Substances Data: 105688-43-5(Hazardous Substances Data)

Upstream product

• 645-96-5 Benzeneselenol 
• 105688-42-4 C₁₁H₉ClO₂ 
• 4440-01-1 lithium phenylacetylide 
• 10229-11-5 4-phenyl-but-3-yn-1-ol 

Downstream Products

• 6285-99-0 (E)-benzylidenedihydro-2(3H)-furanone 

Relevant articles and documents

Synthesis of γ- and δ-Lactones by Free-Radical Annelation of Se-Phenyl Selenocarbonates

A general method for the synthesis of γ- and δ-lactones through the intramolecular addition of alkoxycarbonyl radicals, formed by reaction of Se-phenylselenocarbonates with n-Bu3SnH, onto carbon-carbon multiple bonds is described.This free-radical cyclization is characterized by high regioselectivity favoring exo addition and by a high ratio of cyclization to reduction.Monocyclic, fused bicyclic, and spirocyclic lactones are formed in good to excellent yield.Use of allyltri-n-butyltin as a chain-transfer agent in the place of n-Bu3SnH affords the corresponding 3-butenyl lactones.