10575-65-2Relevant academic research and scientific papers
(Heptafluoro-1,4-cyclohexadien-1-yl)xenon(II) and (Nonafluorocyclohexen-1-yl)xenon(II) Hexafluoroarsenates: Synthesis, Spectroscopic Characterization and Reactivity of the First Alkenylxenon(II) Compounds
Frohn, Hermann,Bardin, Vadim V.
, p. 1072 - 1074 (2007/10/02)
The first alkenylxenon(II) compounds: (heptafluoro-1,4-cyclohexadien-1-yl)xenon(II) hexafluoroarsenate +-1,4-C6F7>- and (nonafluorocyclohexen-1-yl)xenon(II) hexafluoroarsenate +-C6F9>- were
POLYFLUOROCYCLOALKENES. PART XVIII. ARYL ADDUCTS OF DECAFLUOROCYCLOHEXENE
Coe, Paul L.,Oldfield, David,Tatlow, John Colin
, p. 453 - 460 (2007/10/02)
Decafluorocyclohexene reacted slowly with aniline to give 1-phenylamino-3-phenyliminoheptafluorocyclohex-1-ene, which was hydrolysed by hydrochloric acid to 3-phenylaminoheptafluorocyclohex-2-enone.Decafluorocyclohexene reacted stepwise with phenyl lithium, giving 1-phenylnonafluorocyclohexene and thence 1,2-diphenyloctafluorocyclohexene: the former product was attacked slowly by pentafluorophenyl lithium at -40 deg C affording 1-pentafluorophenyl-1-phenyloctafluorocyclohexene.Phenyl lithium reacted sluggishly with bis(pentafluorophenyl)octafluorocyclohexene to give 1-pentafluorophenyl-2-(2',3',5',6'-tetrafluoro-1'-biphenylyl)octafluorocyclohexene and 1,2-bis(2',3',5',6'-tetrafluoro-1'-biphenyl)octafluorocyclohexene. 1,2-Diphenyloctafluorocyclohexene and 1,2-bis(pentafluorophenyl)octafluorocyclohexene were fluorinated by cobalt(III) fluoride to give the olefin, 1,2-bis(undecafluorocyclohexyl)octafluorocyclohexene.
