10575-69-6

Upstream product

• 559-40-0 octaperfluorocyclopentene 
• 591-51-5 phenyllithium 
• 108-86-1 bromobenzene 
• 706-79-6 1,2-dichloro-3,3,4,4,5,5-hexafluorocyclopentene 
• 98-80-6 phenylboronic acid 

Relevant academic research and scientific papers

Synthesis of photochromic diarylethenes using a microflow system

An effective method for the synthesis of photochromic diarylethenes based on microflow systems has been developed, and the synthesis of unsymmetrical diarylethenes which is difficult to achieve using conventional macro batch systems, has been accomplished. The Royal Society of Chemistry.

FLUORINE-CONTAINING AROMATIC COMPOUNDS AND PRODUCTION METHODS THEREOF

PROBLEM TO BE SOLVED: To provide organic semiconductor materials which are applicable to both a dry process and a wet process and have high carrier mobility. SOLUTION: There are provided fluorine-containing fused polycyclic aromatic compounds in which a (CF2)n saturated ring with n being 2-4 is fused, such as fluorine-containing aromatic compounds of the formulas in the figure. COPYRIGHT: (C)2015,JPOandINPIT

Synthetic protocol for diarylethenes through Suzuki-Miyaura coupling

The synthesis of a variety of diarylethenes through the Suzuki-Miyaura coupling reaction of 1,2-dichlorohexafluorocyclopentene with arylboronic acids and esters has been developed. Thiophenes with various substituents such as cyano and ester functionalities can be incorporated.

Reaction of octafluorocyclopentene with various carbon nucleophiles

The treatment of octafluorocyclopentene with organolithium reagents gave the corresponding symmetrical disubstituted perfluorocyclopentenes in good to high yields. The reaction with Grignard reagents led to the monosubstituted perfluorocyclopentenes, which were subjected to the further nucleophilic substitution reaction using another Grignard or aryllithium reagents, unsymmetrical disubstituted perfluorocyclopentenes being obtained in high yields.