1057669-30-3Relevant academic research and scientific papers
Diazonamide support studies: Stereoselective formation of the C10 chiral center in both the CDEFG and AEFG fragments
Lin, Jinzhen,Gerstenberger, Brian S.,Stessman, Nhu Y. T.,Konopelski, Joseph P.
supporting information; experimental part, p. 3969 - 3972 (2009/05/30)
(Chemical Equation Presented) The synthesis of both the AEFG macrolactam and the CDEFG bis-indole/tyrosine units found in the marine natural product diazonamide A is presented. Key to the success of the synthesis is the highly stereoselective direct C-arylation of an oxindole by an aryllead(IV) reagent derived from tyrosine.
