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(C5H4Si(C6H5)3)(CO)2ReH(1-)*Li(1+)=[(C5H4Si(C6H5)3)(CO)2ReH]Li is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

105795-82-2

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105795-82-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 105795-82-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,5,7,9 and 5 respectively; the second part has 2 digits, 8 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 105795-82:
(8*1)+(7*0)+(6*5)+(5*7)+(4*9)+(3*5)+(2*8)+(1*2)=142
142 % 10 = 2
So 105795-82-2 is a valid CAS Registry Number.

105795-82-2Upstream product

105795-82-2Relevant academic research and scientific papers

RING- VERSUS METAL-HYDRIDE DEPROTONATION IN cis-(η5-C5H5)(CO)2Re(SiPh3)H: A ROUTE TO cis- AND trans-(η5-C5H4(SiPh3))(CO)2ReH2

Pasman, P.,Snel, J. J. M.

, p. 329 - 336 (2007/10/02)

Deprotonation of cis-(η5-C5H5)(CO)2Re(SiPh3)H by neopentyllithium at -78 deg C in THF gives an anionic species, which is shown by spectroscopic and chemical methods to be ((η5-C5H4(SiPh3))(CO)2ReH)Li.Its formation is explained by initial deprotonation of the cyclopentadienyl ligand, followed by an intramolecular silyl-group migration.Protonation of the anion at room temperature gives trans-(η5-C5H4(SiPh3))(CO)2ReH2.The latter isomerizes to the trans dihydride complex at room temperature (t1/2 12 h).

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