10581-00-7Relevant articles and documents
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McCusker,Reilly
, p. 1583 (1953)
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PdCl2 and NiCl2-catalyzed hydrogen-halogen exchange for the convenient preparation of bromo- and iodosilanes and germanes
Iwata, Arihiro,Toyoshima, Yutaka,Hayashida, Tsuyoshi,Ochi, Takahiko,Kunai, Atsutaka,Ohshita, Joji
, p. 90 - 95 (2007/10/03)
Bromination and iodination of hydrosilanes and germanes were studied. Treatment of hydrosilanes with an excess of ethyl, propyl, or allyl bromide in the presence of a catalytic amount of PdCl2 or NiCl2 gave bromosilanes in good to high yield by hydrogen-halogen exchange. By using methyl, propyl, or allyl iodide as the iodine source, similar iodination of hydrosilanes was readily performed. Halogenation of hydrogermanes also proceeded by similar treatment.