10581-02-9

Upstream product

• 98-13-5 Phenyltrichlorosilane 
• 71-36-3 butan-1-ol 
• 694-53-1 phenylsilane 
• 123-72-8 butyraldehyde 
• 2996-92-1 phenyl trimethylsiloxane 

Downstream Products

• 58890-26-9 1-phenyl-2,8,9-trioxa-1-sila-adamantane 
• 34454-65-4 Chlorbutoxyaethylphenylsilan 
• 34454-68-7 Amino-n-butoxy-aethyl-phenylsilan 
• 34454-66-5 Amino-di-n-butoxy-phenylsilan 
• 6425-92-9 all-cis-1,3,5,7-tetrahydroxy-1,3,5,7-tetraphenylcyclotetrasiloxane 
• 38049-90-0 Tetraphenyltetrakis-(trimethylsiloxy)-cyclotetrasiloxan 
• 18442-75-6 dibutoxy-chloro-phenyl-silane 

Relevant academic research and scientific papers

Copper nanoparticles supported on doped graphenes as catalyst for the dehydrogenative coupling of silanes and alcohols

Copper nanoparticles (NPs) supported on a series of undoped and doped graphene materials (Gs) have been obtained by pyrolysis of alginate or chitosan biopolymers, modified or not with boric acid, containing Cu2+ ions at 900 °C under inert atmosphere. The resulting Cu-G materials containing about 17 wt% Cu NPs (from 10 to 200 nm) exhibit high catalytic activity for the dehydrogenative coupling of silanes with alcohols. The optimal material consisting on Cu-(B)G is more efficient than Cu NPs on other carbon supports.

Charge Modified Porous Organic Polymer Stabilized Ultrasmall Platinum Nanoparticles for the Catalytic Dehydrogenative Coupling of Silanes with Alcohols

Developing an ideal stabilizer to prevent the aggregation of nanoparticles is still a big challenge for the practical application of noble metal nanocatalysts. Herein, we develop a charge (NTf2?) modified porous organic polymer (POP-NTf2) to stabilize ultrasmall platinum nanoparticles. The catalyst is characterized and applied in the catalytic dehydrogenative coupling of silanes with alcohols. The catalyst exhibits excellent catalytic performance with highly dispersed ultrasmall platinum nanoparticles (ca. 2.22?nm). Moreover, the catalyst can be reused at least five times without any performance significant loss and Pt NPs aggregation. Graphic Abstract: [Figure not available: see fulltext.]

Highly efficient etherification of silanes by using a gold nanoparticle catalyst: Remarkable effect of O2

O2 is acting! A nanosized hydroxylapatite-supported Au nanoparticle (NP) catalyst exhibited high activity under aerobic conditions, and various silyl ethers could be obtained from diverse combinations of silanes with alcohols. Moreover, O2 was found to act not as a stoichiometric oxidizing reagent, but as a non-consumed promoter, significantly boosting the catalytic activity of AuNPs (see figure). Copyright

Catalytic Dehydrogenative Coupling of Hydrosilanes with Alcohols for the Production of Hydrogen On-demand: Application of a Silane/Alcohol Pair as a Liquid Organic Hydrogen Carrier

The compound [Ru(p-cym)(Cl)2(NHC)] is an effective catalyst for the room-temperature coupling of silanes and alcohols with the concomitant formation of molecular hydrogen. High catalyst activity is observed for a variety of substrates affording quantitative yields in minutes at room temperature and with a catalyst loading as low as 0.1 mol %. The coupling reaction is thermodynamically and, in the presence of a Ru complex, kinetically favourable and allows rapid molecular hydrogen generation on-demand at room temperature, under air, and without any additive. The pair silane/alcohol is a potential liquid organic hydrogen carrier (LOHC) for energy storage over long periods in a safe and secure way. Silanes and alcohols are non-toxic compounds and do not require special handling precautions such as high pressure or an inert atmosphere. These properties enhance the practical applications of the pair silane/alcohol as a good LOHC in the automotive industry. The variety and availability of silanes and alcohols permits a pair combination that fulfils the requirements for developing an efficient LOHC.

PRODUCTION METHOD FOR ALKOXYSILANES

Provided is a method for efficiently producing alkoxysilanes that are useful as various functional chemicals. In order to produce alkoxysilanes efficiently, an ethoxy- or methoxysilane and an alcohol are caused to react using, as a catalyst, for instance an inorganic solid acid having a regular-pore and/or layered structure. Zeolites, montmorillonites or the like can be used as the inorganic solid acid. When a zeolite is used as the catalyst, the silica/alumina ratio of the zeolite ranges preferably from 5 to 1000. The reaction can be promoted through irradiation of microwaves.

Synthesis and crystal structure of oxo-bridged binuclear titanium complex [{Ti(acac)2Cl}{TiCp2(Cl)}(μ-O)] and its catalytic reactions toward silation of aldehyde

Reaction of [Cp2TiCl2] with two equivalents of 2,4-pentanedione in the presence of one equivalent of NEt3 in CH3CN at room temperature yielded oxo-bridged binuclear titanium complex [{Ti(acac)2Cl}{TiC

Hydrolytic Etherification of Phenyltrichlorosilane and Structure of Reaction Products

Hydrolytic etherification of phenyltrichlorosilane by C1-C4 primary alcohols was studied. The effect of the concentration and nature of alcohol on the structure and properties of oligomeric polyphenyl-alkoxysilanes were examined.