105823-42-5

Basic information

• Product Name: Acetic acid (1S,3S)-3-[(6aR,7R,9aR)-7-((R)-1,5-dimethyl-hexyl)-6a-methyl-6,6a,7,8,9,9a-hexahydro-1H,5H-indeno[4,5-e][1,2]oxazin-2-yl]-3-methyl-4-oxo-cyclohexyl ester
• CAS NO: 105823-42-5
• Molecular Weight: 471.681
• Mol File: 105823-42-5.mol

Chemical Properties

• CAS DataBase Reference: Acetic acid (1S,3S)-3-[(6aR,7R,9aR)-7-((R)-1,5-dimethyl-hexyl)-6a-methyl-6,6a,7,8,9,9a-hexahydro-1H,5H-indeno[4,5-e][1,2]oxazin-2-yl]-3-methyl-4-oxo-cyclohexyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid (1S,3S)-3-[(6aR,7R,9aR)-7-((R)-1,5-dimethyl-hexyl)-6a-methyl-6,6a,7,8,9,9a-hexahydro-1H,5H-indeno[4,5-e][1,2]oxazin-2-yl]-3-methyl-4-oxo-cyclohexyl ester(105823-42-5)
• EPA Substance Registry System: Acetic acid (1S,3S)-3-[(6aR,7R,9aR)-7-((R)-1,5-dimethyl-hexyl)-6a-methyl-6,6a,7,8,9,9a-hexahydro-1H,5H-indeno[4,5-e][1,2]oxazin-2-yl]-3-methyl-4-oxo-cyclohexyl ester(105823-42-5)

Safety Data

• Hazardous Substances Data: 105823-42-5(Hazardous Substances Data)

Upstream product

• 101039-53-6 C₃₁H₄₉NO₄ 
• 101039-48-9 Acetic acid (3S,5R,8S,13R,14S,17R)-17-((R)-1,5-dimethyl-hexyl)-6-[(E)-hydroxyimino]-5,13-dimethyl-2,3,4,5,6,7,8,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester 
• 17756-93-3 3β-acetoxy-5-methyl-19-nor-5β-cholest-9(10)-en-6-one 
• 105817-43-4 C₃₁H₄₉NO₆ 
• 105804-64-6 Acetic acid (1S,3S)-3-[(6aR,7R,9aS,9bS)-7-((R)-1,5-dimethyl-hexyl)-4a-hydroxy-6a-methyl-5,6,6a,7,8,9,9a,9b-octahydro-1H,4aH-indeno[4,5-e][1,2]oxazin-2-yl]-3-methyl-4-oxo-cyclohexyl ester 
• 101039-49-0 Acetic acid (1S,3S)-3-{2-[(1R,3aS,4S,7aR)-1-((R)-1,5-dimethyl-hexyl)-7a-methyl-5-oxo-octahydro-inden-4-yl]-1-[(E)-hydroxyimino]-ethyl}-3-methyl-4-oxo-cyclohexyl ester 

Relevant articles and documents

Synthesis of 8-methylene-des-AB-cholestan-9-one by cholesterol degradation

The short synthetic route from 3β-acetoxy-5β-methyl-19-norcholest-9(10)-en-6-one (1) to 8-methylene-des-AB-cholestan-9-one (8) is described.Compound 8 is a convenient intermediate for synthesis of relatives of vitamin D3 by the A CD route.

THE CONVENIENT ROUTE TO CD FRAGMENT FOR THE SYNTHESIS OF VITAMIN D3 RELATIVES

The efficient degradation of 1 to the α-methylene ketone 4 is described.Compound 4 was then converted to the allylic alcohol 8a- the precursor of vitamin D3 relatives.