105836-70-2Relevant academic research and scientific papers
DIFFERENTIAL BRIDGING IN THE SOLVOLYSIS OF 6- AND 7-SUBSTITUTED 2-EXO- AND 2-ENDO-NORBORNYL p-TOLUENESULFONATES
Flury, Peter,Grob, Cyril A.
, p. 3195 - 3198 (2007/10/02)
The large difference between the reaction constants ρI for the solvolysis of the 6-exo- and 7-anti-substituted norbornyl tosylates 3 and 7, respectively, is further proof for the hypothesis that 2-norbornyl cations are anisotropic with regard to the transmission of polar effects and that through space induction involves graded bridging.
