105855-00-3Relevant academic research and scientific papers
Diphenyl diselenide-assisted α-phenylthiolation of carbonyl compounds with diphenyl disulfide
Anbou, Hiroaki,Umeda, Rui,Nishiyama, Yutaka
experimental part, p. 1248 - 1250 (2012/01/31)
For the cesium carbonate-catalyzed α-phenylthiolation of carbonyl compounds with diphenyl disulfide, the yields of the α-phenylthio carbonyl compounds were dramatically improved by the addition of a catalytic amount of diphenyl diselenide.
Replacement of the Activated Nitro Group by a Phenylthio Group
Miyake, Hideyoshi,Yamamura, Kimiaki
, p. 89 - 92 (2007/10/02)
The nitro group, activated by a carbonyl group, alkoxycarbonyl group or a phenyl group, can be replaced by a phenylthio group in the reaction with benzenethiol or its potassium salt.This reaction proceeds in the electron transfer mechanism, and is applicable to the general syntheses of α-phenylthio ketones, α-phenylthio carboxylic esters and α-phenylthio alkylbenzenes from primary nitro compounds.
Asymmetric Sulfenylation of Tin(II) Enolates of Ketones and 3-Acyl-2-oxazolidones. Application to the Synthesis of Optically Active Epoxides
Yura, Takeshi,Iwasawa, Nobuharu,Clark, Richard,Mukaiyama, Teruaki
, p. 1809 - 1812 (2007/10/02)
In the presence of chiral diamines, the reaction between tin(II) enolates of ketones or 3-acyl-2-oxazolidones and thiosulfonates proceeds smoothly to give the corresponding β-keto sulfides with high enetioselectivity.Further, optically active epoxides are prepared from these β-keto sulfides.
