1058682-17-9Relevant academic research and scientific papers
Stereoselective titanium-mediated aldol reactions of α-benzyloxy methyl ketones
Pellicena, Miquel,Solsona, Joan G.,Romea, Pedro,Urpi, Felix
, p. 10338 - 10350,13 (2012/12/12)
Good levels of 1,4-anti asymmetric induction are obtained in the TiCl 3(i-PrO)-mediated aldol reaction of chiral α-benzyloxy methyl ketones with a wide array of aldehydes. This methodology represents a new approach to substrate-controlled acetate aldol reactions capable of providing highly functionalized fragments in a straightforward manner, which may be useful in the design of more efficient syntheses.
Stereoselective titanium-mediated aldol reactions of α-benzyloxy methyl ketones
Pellicena, Miquel,Solsona, Joan G.,Romea, Pedro,Urpí, Fèlix
, p. 10338 - 10350 (2013/01/15)
Good levels of 1,4-anti asymmetric induction are obtained in the TiCl 3(i-PrO)-mediated aldol reaction of chiral α-benzyloxy methyl ketones with a wide array of aldehydes. This methodology represents a new approach to substrate-controlled acetate aldol reactions capable of providing highly functionalized fragments in a straightforward manner, which may be useful in the design of more efficient syntheses.
