105877-23-4

Basic information

• Product Name: (PtCl₂(C₅H₄N)CH₂NCH(C₆H₅))
• CAS NO: 105877-23-4
• Molecular Weight: 462.238
• Mol File: 105877-23-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (PtCl₂(C₅H₄N)CH₂NCH(C₆H₅))(CAS DataBase Reference)
• NIST Chemistry Reference: (PtCl₂(C₅H₄N)CH₂NCH(C₆H₅))(105877-23-4)
• EPA Substance Registry System: (PtCl₂(C₅H₄N)CH₂NCH(C₆H₅))(105877-23-4)

Safety Data

• Hazardous Substances Data: 105877-23-4(Hazardous Substances Data)

Upstream product

• 12012-50-9 potassium trichloro(ethene)platinate(II) 
• 88328-13-6 1-phenyl-N-(2-(pyridin-2-yl)methyl)methanimine 

Relevant articles and documents

COMPLEXATION D'IMINOPYRIDINES PAR LE SEL DE ZEISE: VOIE D'ACCES A DES CONJUGUES ESTRADIOL-cis-DICHLORO PLATINE. ETUDE STRUCTURALE DU COMPLEXE cis-PtCl2,H20

In order to synthesize penta- and hexa-gonal platinum(II) metallocycles, bidentate ligands such as iminopyridines (L) have been prepared and characterized.The (2-pyridil)CH=NR1 and (2-pyridil)CH2N=CR1R2 ligands react with Zeise's salt to afford directly the pentagonal chelates PtCl2L.Their structure and the cis-stereochemistry were shown by the usual spectroscopic methods and for cis-PtCl2,H2O by an X-ray diffraction study.On the other hand, the (2-pyridil)(CH2)2N=CR1R2 ligands do not afford the expected hexagonal metallocycles; instead, after complexation at the nitrogen atom of the imine they give rise to the (2-pyridil)ethylamine complex formed after hydrolysis of the coordinated ligands.Complexes trans-1R2>-PtCl2 represent when R1 is estradiol a model for "cytotoxic with delayed activity".