105884-41-1Relevant academic research and scientific papers
Selective Synthesis of Binuclear and Trinuclear Phthalocyanines Covalently Linked by a One Atom Oxygen Bridge
Greenberg, Shafrira,Marcuccio, Sebastian M.,Leznoff, Clifford C.,Tomer, Kenneth B.
, p. 406 - 409 (2007/10/02)
The diiminoisoindolines obtained from 4-neopentoxyphthalonitrile and bis ether gave, in a mixed condensation reaction, binuclear and trinuclear phthalocyanines covalently linked by one atom oxy bridges with the dimer predominating.The underivatized 4-neopentoxyphthalonitrile condensed with the diiminoisoindoline of bis ether in a cross reaction to give the same dimer and trimeric phthalocyanines but the trimer predominated in this reaction.A cobalt derivative of bis-2- ether, the binuclearphthalocyanine, was prepared.All phthalocyanines exhibited parent ions in their fast atom bombardment mass spectra.
