105916-59-4Relevant academic research and scientific papers
Reactions of Metal and Metalloid Compounds with Polyfunctional Molecules, XL Synthesis of N,N',N''-Trialkoxy- and N,N',N''-Tris(amino)borazines
Meller, Anton,Armbrecht, Michael
, p. 1 - 8 (2007/10/02)
N,N',N''-Trimethoxyborazines (-BX-NOMe-)3 (1: X = Cl, 2: X = OMe) are obtained from MeON(SiMe3)2 and Cl2BX.With NaOCMe3 or LiCMe3 1 gives the derivatives 3 (X = OCMe3) and 4 (X = CMe3), respectively.Reaction of PhBCl2 with MeON(SiMe3)2 leads to the 1,2,4,3,5-oxadiazadiborolane derivative 5.With 2 equivalents of Me2BBr Me2BON(SiMe3)BMe2 (6) is obtained.The N,N',N''-tris(amino)borazine (-BOMe-NNMe2-)3 (13) is made from Me2NN(SnMe3)2 and Cl2BOMe. 2 and 13 readily give condensed products.
