105930-88-9

Upstream product

• 79999-47-6 tri-O-(tert-butyldimethylsilyl)-D-glucal 
• 2449-05-0 dibenzyl azodicarboxylate 
• 79999-47-6 (2R,3R,4R)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-3,4-dihydro-2H-pyran 
• 2449-05-0 dibenzyl azodicarboxylate 

Downstream Products

• 115828-08-5 C₃₄H₅₂N₂O₈Si₂ 
• 105930-93-6 C₄₁H₇₀N₂O₉Si₃ 
• 2771-48-4 methyl 2-acetamido-3,4,6-O-triacetyl-2-deoxy-β-D-glucopyranoside 
• 115828-05-2 C₅₂H₈₆N₂O₁₄Si₃ 
• 115828-12-1 C₄₀H₆₇⁽²⁾HN₂O₈Si₃ 
• 115828-11-0 C₄₀H₆₈N₂O₈Si₃ 
• 115828-10-9 C₄₂H₇₀N₂O₁₀Si₃ 
• 115828-09-6 C₆₇H₁₁₄N₂O₉Si₃ 
• 105930-93-6 Methyl 2-<1,2-bis<(phenylmethoxy)carbonyl>hydrazino>-2-deoxy-3,4,6-tris-O-<(1,1-dimethylethyl)dimethylsilyl>-Sb-D-glucopyranoside 

Relevant academic research and scientific papers

CYCLOADDITION REACTION OF BIS(TRICHLOROETHYL)AZODICARBOXYLATE AND GLYCALS: PREPARATION OF A C1-C1 2-AMINO DISACCHARIDE

Bis(trichloroethyl)azodicarboxylate is an efficient diene in the cycloaddition reaction with glycals.It offers several advantages over the previously described dibenzyl azodicarboxylate (DBAD) which was used to prepare 2-amino glycosides.

Cycloaddition Reaction of Dibenzyl Azodicarboxylate and Glycals

The cycloaddition reaction of dibenzyl azodicarboxylate and glycals allows the stereoselective introduction of an amino function at C-2 of a carbohydrate.Very good results were obtained with both furanoid and pyranoid glycals, except when triacetylglucal (TAG) was used as the substrate.In some instances the course of the reaction was found to be concentration dependent.