105938-01-0

Upstream product

• 1461-22-9 tributyltin chloride 

Downstream Products

• 130912-27-5 (2R,3S,4R)-3,4-bis(benzyloxy)-2-((benzyloxy)methyl)-6-phenyl-3,4-dihydro-2H-pyran 
• 142270-10-8 1,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-1-C-(4-methoxyphenyl)-D-arabino-hex-1-enitol 
• 130912-32-2 1,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-1-C-vinyl-D-arabino-hex-1-enitol 
• 142270-14-2 2,6:7,11-dianhydro-5,8-dideoxy-1,3,4,9,10,12-hexakis-O-benzyl-D-erythro-L-gulo-dodeco-5,7-dienitol 
• 142270-17-5 1,4-di-(1,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-D-arabino-hex-1-enit-1-yl)benzene 
• 130912-29-7 1,5-anhydro-1-C-benzyl-3,4,6-tri-O-benzyl-2-deoxy-D-arabino-hex-1-enitol 
• 130940-55-5 1,5-anhydro-3,4,6-tri-O-benzyl-2-deoxy-1-C-(4-nitrobenzoyl)-D-arabino-hex-1-enitol 
• 134268-85-2 (1S,2R)-2-((4R,5S,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-yl)-cyclohexanol 
• 134268-85-2 (1S,2S)-2-((4R,5S,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-yl)-cyclohexanol 
• 1374871-04-1 (2R,3R,4R,E)-1,3,4-tris(benzyloxy)dec-5-en-2-ol 
• 130912-40-2 (2R,3R,4R,5R,6R,2'S,3'R,4'R,5'R,6'R)-4,5,4',5'-Tetrakis-benzyloxy-6,6'-bis-benzyloxymethyl-octahydro-[2,2']bipyranyl-3,3'-diol 
• 130912-40-2 2,6:7,11-dianhydro-1,3,4,9,10,12-hexa-O-benzyl-D-erythro-L-galacto-L-gulo-dodecitol 
• 142270-15-3 3,4,6-tri-O-benzyl-1-C-phenyl-α-D-glucopyranose 
• 121386-95-6 (2R,3S,4R,6R)-3,4-bis(benzyloxy)-2-((benzyloxy)methyl)-6-phenyltetrahydro-2H-pyran 

Relevant academic research and scientific papers

Synthesis and Pd-catalyzed coupling of1-C-stannylated glycals

1-Tributylstannyl glycals were applied as versatile tools in the Pd(0)-mediated synthesis of glycal phthalonitrile conjugates. Likewise, selective homo-coupling of 1-tributylstannyl glycals furnishing C1-C1’ linked glycal dimers was investigated by using Pd(II)-species. For both Stille type couplings the rate-accelerating effect of copper(I) thiophene-2-carboxylate (CuTC) was exploited. The synthesis of stannylated glycal precursors was significantly improved by establishing a one-pot two-step procedure via glycosyl sulfoxides.