106019-01-6Relevant articles and documents
Radical Cyclization of Trifluoromethyl-substituted Carbon: A Facile Preparation of Trifluoromethylated Five-membered Ring Compounds
Watanabe, Yoshihiko,Yokozawa, Tsutomo,Takata, Toshikazu,Endo, Takeshi
, p. 431 - 434 (1988)
α-Trifluoromethyl carbon radicals, generated by the tributyltin radical, added intramolecularly to oleginic double bonds to afford the trifluoromethyl-substituted five-membered ring compounds.
Efficient Carbonyl Addition of Polyfluorochloroethyl, -ethylidene, and -ethenyl Units by Means of 1,1,1-Trichloro-2,2,2-trifluoroethane and Zinc
Fujita, Makoto,Hiyama, Tamejiro
, p. 4377 - 4384 (2007/10/02)
Thermally stable zinc carbenoid CF3CCl2ZnCl was prepared from 1,1,1-trichloro-2,2,2-trifluoroethane and zinc powder in N,N-dimethylformamide and was allowed to add to carbonyls of aldehydes and α-keto esters in excellent yields to give 1-substituted 2,2-d
EFFICIENT CARBON-CARBON BOND FORMATION WITH THERMALLY STABLE 1,1-DIHALO-2,2,2-TRIFLUOROETHYLZINC REAGENT
Fujita, Makoto,Morita, Tomoe,Hiyama, Tamejiro
, p. 2135 - 2138 (2007/10/02)
The zinc carbenoids CF3CX2ZnX, prepared from CF3CX3 and zinc powder in dimethylformamide, were found thermally stable to add to aldehyde carbonyls in excellent yields.