106032-26-2Relevant academic research and scientific papers
Ring transformation of 1,2,3,5,6,7-hexahydropyrrolizinium perchlorates into 1-substituted 5-oxoperhydroazocines
Sumoto,Mibu,Irie,Abe,Miyano
, p. 577 - 580 (2007/10/02)
A facile ring transformation of 1,2,3,5,6,7-hexahydropyrrolizinium perchlorates (1 and 2) to 1-substituted 5-oxoperhydroazocines (5) is described. The spectroscopic and chemical properties of these products are also presented.
A NEW ROUTE TO 1-ACYL-5-OXOPERHYDROAZOCINE CORE USING 1,2,3,5,6,7-HEXAHYDROPYRROLIZINIUM PERCHLORATES
Miyano, Seiji,Mibu, Nobuko,Irie, Michiko,Sumoto, Kunihiro
, p. 2121 - 2126 (2007/10/02)
A convenient simple method for the synthesis of 1-substituted 5-oxoperhydroazocinea (1) is described.The method consists of N-acylation of 5-oxoperhydroazocine which is one of the tautomers of the pseudobase (3) generated by the treatment of 1,2,3,5,6,7-hexahydropyrrolizinium perchlorate with aqueous alkali.
