10605-31-9Relevant academic research and scientific papers
Infrared Multiphoton Decomposition of Diethylnitramine
Lazarou, Yannis G.,King, Keith D.,Papagiannakopoulos, Panos
, p. 7351 - 7355 (1992)
Irradiation of gaseous diethylnitramine with infrared radiation from a pulsed CO2 laser under collision-free and collisional conditions resulted in the formation of diethylnitrosamine as the main product along with nitrogen dioxide, nitric oxide, formaldoxime, and diethyl nitroxide.Scavenging experiments with Cl2, NO, and (CD3)2NNO2 molecules have shown that the primary channel of unimolecular dissociation of diethylnitramine molecules is the scission of the N-NO2 bond, with a steady-state rate constant of 105.2 +/- 0.1(I/MW cm-2) s-1 for laser intensities in the range 3-15 MW cm-2 at an irradiation frequency of 1075.9 cm-1.A qualitative analysis of the chemical mechanism leading to the formation of final products as well as the importance of the diethylamino radical oxidation reactions is presented.
RADICAL PRODUCTS OF HYDROXYLAMINES, NITRONES AND SPIN ADDUCTS IN THE PROCESS OF GRADUAL OXIDATION WITH COORDINATED PEROXY-RADICALS
Cholvad, Vlado,Stasko, Andrej,Tkac, Alexander,Buchanenko, Anatolii L.,Malik, Lubomir
, p. 823 - 832 (2007/10/02)
Hydroperoxides and cobalt-coordinated peroxy-radicals oxidize hydroxylamines as e.g.Et2NOH, (PhCH2)2NOH, PhCH2PhNOH to the respective nitrones, and the spin adducts - nitrone and peroxy-radical - are formed.In contrast to hydroperoxides the coordinated peroxy radicals can oxidize the formed spin adducts, the methylene or methine groups next to nitrogen being converted into carbonyl groups.The radical intermediates corresponding to individual steps of the gradual oxidation have been identified by means of EPR spectra.
