1061-78-5Relevant academic research and scientific papers
Thermolytic Transformation of Steroidal Nitroimines
Ahmad, M. S.,Raza, S. K.
, p. 259 - 260 (2007/10/02)
Thermolysis of 6-nitroimino-5α-cholestan-3β-yl acetate (I), 6-nitroimino-5α-cholestane (VII) and 7-nitroiminocholest-5-en-3β-yl chloride (XII) in refluxing xylene affords a mixture of products in the case of I and VII and a chlorine-free product in the case of XII.The known products have been characterized by direct comparison while unknown products by elemental analyses and spectral data.
Reduction of Steroidal Nitroolefins with Zinc-Acetic Acid without Added Water
Ahmad, M. S.,Raza, S. K.
, p. 579 - 580 (2007/10/02)
Zinc-acetic acid reduction (without added water) of steroidal nitroolefins (I-III) leads to the formation of respective N-acetylated enamines (X-XII) alongwith the parent ketones (IV-VI) and the oximes (VII-IX).These products have been identified on the basis of their spectral properties and by comparison with authentic samples where available.
