1061178-54-8Relevant articles and documents
Thiazole-annelated imidazolium salts: A new architecture for N-heterocyclic carbenes
Lohre, Claudia,Froehlich, Roland,Glorius, Frank
scheme or table, p. 2221 - 2228 (2009/04/06)
A short synthesis of thiazole-annelated imidazolium salts is presented. Deprotonation of these salts allowed the formation of new N-heterocyclic carbenes (NHCs) and the investigation of their respective electronic properties, which were determined by X-ray crystal structure analysis and IR spectroscopy of the corresponding iridium carbonyl complexes. Finally, the ability of these NHCs to form the corresponding palladium complexes was demonstrated. Georg Thieme Verlag Stuttgart.