106174-97-4Relevant academic research and scientific papers
Selective hydrogenation of conjugated unsaturated ketones containing a hydroxyaryl substituent in the β-position
Kovalenko,Pratsko
, p. 24 - 28 (2017)
A high selectivity was achieved in the Ni2B-catalyzed hydrogenation of α,β-unsaturated ketones containing a hydroxyaryl (phenolic) substituent in the β-position. The developed hydrogenation procedure was used to synthesize natural compounds of the phenylpropane series and their structural analogs.
Studies towards the diastereoselective spiroannulation of phenolic derivatives
Plourde, Guy L.
, p. 3597 - 3599 (2007/10/03)
The oxidative spiroannulation of simple phenols bearing a chiral center was carried out. Good yields (61-83%) of spirocompounds were obtained. An increase in diastereomeric ratios from 55/45 to 81/19 was observed as the steric factor surrounding the chiral carbon increased.
