106251-88-1Relevant articles and documents
Acylnitrilium ions. Versatile new intermediates for the synthesis of highly functionalized heterocycles
Luedtke,Westling,Livinghouse
, p. 2209 - 2222 (2007/10/02)
Acylnitrilium ions, generated by the exposure of α-ketoimidoyl chlorides to AgBF4, readily engage suitably disposed sites of molecular unsaturation in cyclization reactions leading to heterocyclic ring systems. This novel method for annulation
A Comparative Investigation of the Reactions of α-Metallomethyl Isocyanides with α,β-Unsaturated Ketones
Westling, Mark,Livinghouse, Tom
, p. 391 - 393 (2007/10/02)
The nucleophilic addition of lithiomethyl isocyanide to representative α,β-unsaturated ketones has been examined.The ratio of 1,2- to 1,4-addition is dependent upon the inclusion of ligating cosolvents.In addition, the reactions of alternative α-metallomethyl isocyanides with α,β-unsaturated ketones have been studied.