106262-75-3Relevant academic research and scientific papers
Transition-Metal Catalyzed Stereoselective γ-Arylation and Friedel-Crafts Alkylation: A Concise Synthesis of Indenes
Ramesh, Karu,Satyanarayana, Gedu
supporting information, p. 3235 - 3242 (2020/06/02)
A highly stereoselective [Pd]-catalyzed arylation of tert-alkenols, is presented and applied to the synthesis of indenes using intramolecular Friedel–Crafts alkylation sequence. The initial Heck reaction is performed by using water as the green solvent. A simple acid triggers intramolecular alkylation in short reaction times at room temperature. Notably, indenes have been accomplished using a single column chromatography technique.
Palladium-catalyzed reduction of alkynes employing HSiEt3: stereoselective synthesis of trans- and cis-alkenes
Luo, Fang,Pan, Changduo,Wang, Wenhui,Ye, Zhishi,Cheng, Jiang
supporting information; experimental part, p. 1399 - 1403 (2010/04/04)
The palladium-catalyzed semi-hydrogenation of alkynes to trans- or cis-alkenes employing HSiEt3 as the reductant is developed. The CuSO4 played a significant role for the trans/cis stereoselectivity. The labeling study revealed that the two olefinic hydrogen atoms came from HSiEt3 and H2O, respectively.
Stereospecific Desulfinylation of α,β-Epoxy Sulfoxides with Butyllithium. A New Synthesis of Epoxides and Allylic Alcohols from Carbonyl Compounds
Satoh, Tsuyoshi,Kaneko, Youhei,Yamakawa, Koji
, p. 2463 - 2470 (2007/10/02)
Desulfinylation of α,β-epoxysulfoxides, easily prepared from carbonyl compounds and 1-chloroalkyl phenyl sulfoxide, with 1 equivalent of butyllithium at low temperature gave epoxides in good yields.The similar α,β-epoxy sulfoxides having an arylmethyl gro
A NOVEL SYNTHESIS OF EPOXIDES AND ALLYLIC ALCOHOLS FROM CARBONYL COMPOUNDS THROUGH α,β-EPOXY SULFOXIDES
Satoh, Tsuyoshi,Kaneko, Youhei,Yamakawa, Koji
, p. 2379 - 2382 (2007/10/02)
Treatment of α,β-epoxy sulfoxides, easily prepared from carbonyl compounds with 1 equivalent of n-butyllithium at -100 deg C gave the desulfinated epoxides in good yields.The similar α,β-epoxy sulfoxides having arylmethyl group at α-position, on treatment
