106319-08-8Relevant articles and documents
Formal ring-opening/cross-coupling reactions of 2-pyrones: Iron-catalyzed entry into stereodefined dienyl carboxylates
Sun, Chang-Liang,Fuerstner, Alois
, p. 13071 - 13075 (2013)
Open access: Despite the exceptional level of sophistication in cross-coupling chemistry, reactions of substrates that incorporate the leaving group as an integral part into a heterocyclic scaffold are scarce. The title reaction outlines the utility of this reaction format (see scheme; acac=acetylacetonate), provides a convenient entry into stereodefined diene carboxylates, and adds a new chapter to the field of iron catalysis. Copyright
A Versatile Synthesis of α-Pyrones
Dieter, R. Karl,Fishpaugh, Jeffrey R.
, p. 4439 - 4441 (2007/10/02)
The α-oxoketene dithioacetal functionality is exploited in a versatile and efficient synthesis of annulated and simple α-pyrones.The alkyl substitution pattern about the α-pyrone ring can be modified at all four olefinic carbon atoms in a systematic manner.