106334-37-6

Basic information

• Product Name: Cyclohexanecarboxylic acid, 1-methyl-2-nitro-, methyl ester, cis- (9CI)
• Synonyms: Cyclohexanecarboxylic acid, 1-methyl-2-nitro-, methyl ester, cis- (9CI)
• CAS NO: 106334-37-6
• Molecular Formula: C₉H₁₅NO₄
• Molecular Weight: 201.2197
• Product Categories: AMINOACID
• Mol File: 106334-37-6.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclohexanecarboxylic acid, 1-methyl-2-nitro-, methyl ester, cis- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanecarboxylic acid, 1-methyl-2-nitro-, methyl ester, cis- (9CI)(106334-37-6)
• EPA Substance Registry System: Cyclohexanecarboxylic acid, 1-methyl-2-nitro-, methyl ester, cis- (9CI)(106334-37-6)

Safety Data

• Hazardous Substances Data: 106334-37-6(Hazardous Substances Data)

Upstream product

• 106334-33-2 2-methyl-2-carbomethoxycyclohexanone oxime 
• 106334-34-3 2-Bromo-1-methyl-2-nitro-cyclohexanecarboxylic acid methyl ester 
• 106334-27-4 2-(2-nitropropyl)-1,3-dioxolane 

Relevant articles and documents

UNSYMMETRICAL CONNECTIVE OLEFINATION BY KORNBLUM NITRO-SYNTHESIS : APPLICATIONS IN PHYTUBERIN CHEMISTRY

Kornblum unsymmetrical olefin synthesis employing radical-anion chain crossed-coupling (light catalysed) of a mono- and a gem-di-nitro-compound, followed by reductive NO2 removal, is examined in the context of a hindered olefin structure required for phytuberin synthesis.Whilst successful for a tetrasubstituted olefin model (for which a Witting approach failed), increasing substitution on the β-position of the mono-nitro component supressed the coupling reaction, presumably for steric reasons.An alternative coupling involving a bromonitrocyclohexane and a mononitroacetal caused symmetrical coupling of the mononitro-component in high yield, rather than a crossed reaction.Reductive elimination (using Na2S/DMF) from either rac.- or meso- 1,2-dinitro-1,2-diphenylethane leads to (E)-stilbene 98percent (E) > probably through a stabilised radical or anion.A convenient preparation of triphenylisoxazoline-N-oxide is reported.