106336-34-9Relevant academic research and scientific papers
The use of nafion-h to promote epoxide cyclizations
Taylor, Stephen K.,Dickinson, Michael G.,May, Scott A.,Pickering, Dacia A.,Sadek, Paul C.
, p. 1133 - 1136 (1998)
Nafion-H is shown to be an effective promoter of epoxide cyclizations to aromatic positions. The reactions can be done by passing a solution of the epoxide through a column packed with Nafion-H, or by stirring a mixture of the compound with the acidic pro
Friedel-crafts cyclialkylations of some epoxides. 2. Stereospecificity, substituent, product, and kinetic studies
Taylor, Stephen K.,Davisson, Mark E.,Hissom Jr., B. Rolf,Brown, Sandra L.,Pristach, Holle A.,Schramm, Scott B.,Harvey, Suzanne M.
, p. 425 - 429 (2007/10/02)
The relative facility of the cyclialkylation of several arylalkyl epoxides was investigated. Stereochemical studies on the cyclialkylation of cis- and trans-2,3-epoxy-5-phenylpentane establish that the stereospecificity of ring formation is as high as 97%
