106377-05-3Relevant academic research and scientific papers
Synthesis of Substituted 1,4-Oxathianes. Mechanistic Details of Diethoxytriphenylphosphorane- and Triphenylphosphine/Tetrachloromethane-Promoted Cyclodehydrations and 13C NMR Spectroscopy
Murray, William T.,Kelly, Jeffery W.,Evans, Slayton A.
, p. 525 - 529 (1987)
Diethoxytriphenylphosphorane (DTPP) initiates stereospecific cyclodehydrations of 2,2'-bis(hydroxyethyl)sulfides to the corresponding 1,4-oxathianes in a single step (70-85percent) by GLC and 13C NMR analyses.The mechanistic details of Ph3P/CCl4- and Ph3P
Mechanistic studies on a sulfoxide transfer reaction mediated by diphenyl sulfoxide/triflic anhydride
Fascione, Martin A.,Adshead, Sophie J.,Mandal, Pintu K.,Kilner, Colin A.,Leach, Andrew G.,Turnbull, W. Bruce
supporting information; experimental part, p. 2987 - 2997 (2012/04/23)
Sulfoxides are frequently used in organic synthesis as chiral auxiliaries and reagents to mediate a wide variety of chemical transformations. For example, diphenyl sulfoxide and triflic anhydride can be used to activate a wide range of glycosyl donors inc
