106400-06-0Relevant academic research and scientific papers
The asymmetric epoxidation of divinyl carbinols: Theory and applications
Smith, David B.,Wang, Zhaoyin,Schreiber, Stuart L.
, p. 4793 - 4808 (2007/10/02)
The asymmetric epoxidation of symmetric divinyl carbinols is illustrative of a reaction process that combines an initial asymmetric synthesis with a subsequent kinetic resolution to provide products with extraordinary levels of enantiomeric purity. The application of this process to the asymmetric synthesis of natural products is presented herein.
Reactions That Proceed with a Combination of Enantiotopic Group and Diastereotopic Face Selectivity Can Deliver Products with Very High Enantimeric Excess: Experimental Support of a Mathematical Model
Schreiber, Stuart L.,Schreiber, Thomas S.,Smith, David B.
, p. 1525 - 1529 (2007/10/02)
A generic class of reactions is described that involve the selective addition of a chiral, nonracemic reagent to one of four heterotopic faces of a substrate that contains a prosterogenic atom (or atoms) equipped with ligands that are enantiotopic and uns
