106409-61-4Relevant academic research and scientific papers
o-Hydroxyarylphosphines and diphosphines: Metallation-rearrangement versus P-O reduction of o-halogenoaryloxyphosphines by sodium
Heinicke, Joachim,Kadyrov, Renat
, p. 131 - 137 (1996)
o-Bromo-and o-chloroaryloxyphosphines 1 may react with sodium in two competing ways: (i) metal halogen exchange followed by rapid intramolecular 1,3-rearrangement to give sodium o-hydroxylato-arylphosphines 2, later converted to their OSiMe3 de
