106426-94-2

Downstream Products

• 126855-85-4 (R_C,R_S)-2-acetoxy-1-p-tolylsulfinylhexane 
• 106426-95-3 Benzoic acid (R)-1-((R)-toluene-4-sulfinylmethyl)-pentyl ester 
• 126856-08-4 1-(4-methylphenylthio)-2-hexanone 
• 126855-93-4 (R,E)-4-acetoxy-1-phenyl-2-octen-1-one 
• 126855-87-6 Acetic acid (R)-1-(chloro-p-tolylsulfanyl-methyl)-pentyl ester 
• 126855-98-9 tert-Butyl-[(R)-1-(chloro-p-tolylsulfanyl-methyl)-pentyloxy]-dimethyl-silane 
• 126855-88-7 Benzoic acid (R)-1-(chloro-p-tolylsulfanyl-methyl)-pentyl ester 
• 126855-94-5 Benzoic acid (R)-1-((E)-3-oxo-3-phenyl-propenyl)-pentyl ester 
• 126855-89-8 Acetic acid (R)-1-[(2-oxo-cyclopentyl)-p-tolylsulfanyl-methyl]-pentyl ester 
• 126855-92-3 Acetic acid (R)-1-(3-oxo-3-phenyl-1-p-tolylsulfanyl-propyl)-pentyl ester 
• 126856-00-6 (R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-p-tolylsulfanyl-octanoic acid ethyl ester 
• 126855-96-7 Acetic acid (R)-1-[(2-oxo-cyclopentyl)-(toluene-4-sulfonyl)-methyl]-pentyl ester 
• 126855-86-5 Trifluoro-acetic acid (R)-2-acetoxy-1-p-tolylsulfanyl-hexyl ester 
• 127211-24-9 Benzoic acid (R)-1-(3-oxo-3-phenyl-1-p-tolylsulfanyl-propyl)-pentyl ester 

Relevant academic research and scientific papers

Highly Enantioselective Rearrangement of (S)-E-α-p-Tolylsulphinyl-α,β-enolates to (R)-E-γ-Hydroxy-α,β-enoates

On treatment with pyridine-camphorsulphonic acid, (S)-E-α-p-tolylsulphinyl-α,β-enoates (4) undergo enantioselectively a sequential prototropic shift and allylic sulphoxide-sulphenate rearrangement to produce (R)-E-γ-hydroxy-α,β-enoates (2) in 64-72percent